The use of [2-C6R4PPh2]− (R = H, F) and related carbanions as building blocks in coordination chemistry

Martin A. Bennett; Suresh K. Bhargava; Nedaossadat Mirzadeh; Steven H. Privér

doi:10.1016/j.ccr.2018.05.008

The use of [2-C₆R₄PPh₂]⁻ (R = H, F) and related carbanions as building blocks in coordination chemistry

Martin A. Bennett, Suresh K. Bhargava^*, Nedaossadat Mirzadeh, Steven H. Privér

^*Corresponding author for this work

Research output: Contribution to journal › Review article › peer-review

13 Citations (Scopus)

Abstract

Over the last half-century, aryl carbanions of the general type [2-C₆R₄ER′₂]⁻ (R = H, F; E = Group 15 element; R′ = various alkyl and aryl groups) have found increasing application as versatile building blocks in the design of novel ligands which, in turn, have played a prominent role in the development of the chemistry of main group and d-block element chemistry. In this review we aim to summarise the main findings and the developments to which they have contributed.

Original language	English
Pages (from-to)	69-128
Number of pages	60
Journal	Coordination Chemistry Reviews
Volume	370
DOIs	https://doi.org/10.1016/j.ccr.2018.05.008
Publication status	Published - 1 Sept 2018

Access to Document

10.1016/j.ccr.2018.05.008

Cite this

@article{4ba426c3068e4cdab05b7d0d35e47268,

title = "The use of [2-C6R4PPh2]− (R = H, F) and related carbanions as building blocks in coordination chemistry",

abstract = "Over the last half-century, aryl carbanions of the general type [2-C6R4ER′2]− (R = H, F; E = Group 15 element; R′ = various alkyl and aryl groups) have found increasing application as versatile building blocks in the design of novel ligands which, in turn, have played a prominent role in the development of the chemistry of main group and d-block element chemistry. In this review we aim to summarise the main findings and the developments to which they have contributed.",

keywords = "Coordination chemistry, Pincer complex, Transition metal, Tripodal complex, ortho-Metallated",

author = "Bennett, {Martin A.} and Bhargava, {Suresh K.} and Nedaossadat Mirzadeh and Priv{\'e}r, {Steven H.}",

note = "Publisher Copyright: {\textcopyright} 2018 Elsevier B.V.",

year = "2018",

month = sep,

day = "1",

doi = "10.1016/j.ccr.2018.05.008",

language = "English",

volume = "370",

pages = "69--128",

journal = "Coordination Chemistry Reviews",

issn = "0010-8545",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - The use of [2-C6R4PPh2]− (R = H, F) and related carbanions as building blocks in coordination chemistry

AU - Bennett, Martin A.

AU - Bhargava, Suresh K.

AU - Mirzadeh, Nedaossadat

AU - Privér, Steven H.

PY - 2018/9/1

Y1 - 2018/9/1

N2 - Over the last half-century, aryl carbanions of the general type [2-C6R4ER′2]− (R = H, F; E = Group 15 element; R′ = various alkyl and aryl groups) have found increasing application as versatile building blocks in the design of novel ligands which, in turn, have played a prominent role in the development of the chemistry of main group and d-block element chemistry. In this review we aim to summarise the main findings and the developments to which they have contributed.

AB - Over the last half-century, aryl carbanions of the general type [2-C6R4ER′2]− (R = H, F; E = Group 15 element; R′ = various alkyl and aryl groups) have found increasing application as versatile building blocks in the design of novel ligands which, in turn, have played a prominent role in the development of the chemistry of main group and d-block element chemistry. In this review we aim to summarise the main findings and the developments to which they have contributed.

KW - Coordination chemistry

KW - Pincer complex

KW - Transition metal

KW - Tripodal complex

KW - ortho-Metallated

UR - http://www.scopus.com/inward/record.url?scp=85047651030&partnerID=8YFLogxK

U2 - 10.1016/j.ccr.2018.05.008

DO - 10.1016/j.ccr.2018.05.008

M3 - Review article

SN - 0010-8545

VL - 370

SP - 69

EP - 128

JO - Coordination Chemistry Reviews

JF - Coordination Chemistry Reviews

ER -

The use of [2-C₆R₄PPh₂]⁻ (R = H, F) and related carbanions as building blocks in coordination chemistry

Abstract

Access to Document

Other files and links

Fingerprint

Cite this

The use of [2-C6R4PPh2]− (R = H, F) and related carbanions as building blocks in coordination chemistry

Abstract

Access to Document

Other files and links

Fingerprint

Cite this

The use of [2-C₆R₄PPh₂]⁻ (R = H, F) and related carbanions as building blocks in coordination chemistry