Thioacyl complexes of molybdenum and tungsten

Darren J. Cook; Anthony F. Hill

doi:10.1039/a701270e

Thioacyl complexes of molybdenum and tungsten

Darren J. Cook^*, Anthony F. Hill

^*Corresponding author for this work

Research School of Chemistry

Research output: Contribution to journal › Literature review › peer-review

28 Citations (Scopus)

Abstract

The reactions of a range of alkylidyne complexes of molybdenum and tungsten [M(≡CR)L_n] with 2-methylthiirane provide the first thioacyl complexes [M(η2-SCR)L_n] of these elements, which serve as precursors for complexes bearing dithiocarboxylate, thioselenocarboxylate, thiolatocarbene and α-thioalkyl ligands and thioacyl-bridged binuclear complexes.

Original language	English
Pages (from-to)	955-956
Number of pages	2
Journal	Chemical Communications
Issue number	10
DOIs	https://doi.org/10.1039/a701270e
Publication status	Published - 21 May 1997

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title = "Thioacyl complexes of molybdenum and tungsten",

abstract = "The reactions of a range of alkylidyne complexes of molybdenum and tungsten [M(≡CR)Ln] with 2-methylthiirane provide the first thioacyl complexes [M(η2-SCR)Ln] of these elements, which serve as precursors for complexes bearing dithiocarboxylate, thioselenocarboxylate, thiolatocarbene and α-thioalkyl ligands and thioacyl-bridged binuclear complexes.",

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year = "1997",

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AU - Cook, Darren J.

AU - Hill, Anthony F.

PY - 1997/5/21

Y1 - 1997/5/21

N2 - The reactions of a range of alkylidyne complexes of molybdenum and tungsten [M(≡CR)Ln] with 2-methylthiirane provide the first thioacyl complexes [M(η2-SCR)Ln] of these elements, which serve as precursors for complexes bearing dithiocarboxylate, thioselenocarboxylate, thiolatocarbene and α-thioalkyl ligands and thioacyl-bridged binuclear complexes.

AB - The reactions of a range of alkylidyne complexes of molybdenum and tungsten [M(≡CR)Ln] with 2-methylthiirane provide the first thioacyl complexes [M(η2-SCR)Ln] of these elements, which serve as precursors for complexes bearing dithiocarboxylate, thioselenocarboxylate, thiolatocarbene and α-thioalkyl ligands and thioacyl-bridged binuclear complexes.

UR - http://www.scopus.com/inward/record.url?scp=0001777608&partnerID=8YFLogxK

U2 - 10.1039/a701270e

DO - 10.1039/a701270e

M3 - Literature review

AN - SCOPUS:0001777608

SN - 1359-7345

SP - 955

EP - 956

JO - Chemical Communications

JF - Chemical Communications

IS - 10

ER -

Thioacyl complexes of molybdenum and tungsten

Abstract

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