Total syntheses of the furanosesquiterpenes crassifolone and dihydrocrassifolone via an Au(I)-catalysed intramolecular Michael addition reaction

Rajeev S. Menon; Martin G. Banwell

doi:10.1039/c0ob00487a

Total syntheses of the furanosesquiterpenes crassifolone and dihydrocrassifolone via an Au(I)-catalysed intramolecular Michael addition reaction

Rajeev S. Menon, Martin G. Banwell

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

The racemic modifications of title natural products 1 and 2 have been synthesised for the first time. The key step was the Au(i)-catalysed conversion of the furanyl-substituted ynone 13 into the annulated furan 14.

Original language	English
Pages (from-to)	5483-5485
Number of pages	3
Journal	Organic and Biomolecular Chemistry
Volume	8
Issue number	24
DOIs	https://doi.org/10.1039/c0ob00487a
Publication status	Published - 21 Dec 2010

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title = "Total syntheses of the furanosesquiterpenes crassifolone and dihydrocrassifolone via an Au(I)-catalysed intramolecular Michael addition reaction",

abstract = "The racemic modifications of title natural products 1 and 2 have been synthesised for the first time. The key step was the Au(i)-catalysed conversion of the furanyl-substituted ynone 13 into the annulated furan 14.",

author = "Menon, \{Rajeev S.\} and Banwell, \{Martin G.\}",

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AU - Banwell, Martin G.

PY - 2010/12/21

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N2 - The racemic modifications of title natural products 1 and 2 have been synthesised for the first time. The key step was the Au(i)-catalysed conversion of the furanyl-substituted ynone 13 into the annulated furan 14.

AB - The racemic modifications of title natural products 1 and 2 have been synthesised for the first time. The key step was the Au(i)-catalysed conversion of the furanyl-substituted ynone 13 into the annulated furan 14.

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U2 - 10.1039/c0ob00487a

DO - 10.1039/c0ob00487a

M3 - Article

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VL - 8

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JO - Organic and Biomolecular Chemistry

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IS - 24

ER -

Total syntheses of the furanosesquiterpenes crassifolone and dihydrocrassifolone via an Au(I)-catalysed intramolecular Michael addition reaction

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