Abstract
Seeing double: Consideration of the biosynthetic origins of incargranineB, which was originally assigned an unprecedented indolo[1.7]naphthyridine structure, led to the proposal of a dipyrroloquinoline framework as a more biosynthetically feasible structure (see scheme; Piv=pivaloyl). This hypothesis was validated by a short biomimetic synthesis of incargranineB.
Original language | English |
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Pages (from-to) | 13273-13275 |
Number of pages | 3 |
Journal | Angewandte Chemie - International Edition |
Volume | 52 |
Issue number | 50 |
DOIs | |
Publication status | Published - 9 Dec 2013 |