Total synthesis of uniflorine A, casuarine, australine, 3-epi-australine, and 3,7-di-epi-australine from a common precursor

Thunwadee Ritthiwigrom; Anthony C. Willis; Stephen G. Pyne

doi:10.1021/jo902355p

Total synthesis of uniflorine A, casuarine, australine, 3-epi-australine, and 3,7-di-epi-australine from a common precursor

Thunwadee Ritthiwigrom, Anthony C. Willis, Stephen G. Pyne

Research output: Contribution to journal › Article › peer-review

92 Citations (Scopus)

Abstract

(Chemical Equation Presented) Aflexible method for the diastereoselective total synthesis of the pyrrolizidine alkaloids uniflorine A, casuarine, australine, and 3-epi-australine and the unnatural epimer 3,7-di-epi-australine from a common chiral 2,5-dihydropyrrole precursor is described.

Original language	English
Pages (from-to)	815-824
Number of pages	10
Journal	Journal of Organic Chemistry
Volume	75
Issue number	3
DOIs	https://doi.org/10.1021/jo902355p
Publication status	Published - 5 Feb 2010

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10.1021/jo902355p

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abstract = "(Chemical Equation Presented) Aflexible method for the diastereoselective total synthesis of the pyrrolizidine alkaloids uniflorine A, casuarine, australine, and 3-epi-australine and the unnatural epimer 3,7-di-epi-australine from a common chiral 2,5-dihydropyrrole precursor is described.",

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AU - Ritthiwigrom, Thunwadee

AU - Willis, Anthony C.

AU - Pyne, Stephen G.

PY - 2010/2/5

Y1 - 2010/2/5

N2 - (Chemical Equation Presented) Aflexible method for the diastereoselective total synthesis of the pyrrolizidine alkaloids uniflorine A, casuarine, australine, and 3-epi-australine and the unnatural epimer 3,7-di-epi-australine from a common chiral 2,5-dihydropyrrole precursor is described.

AB - (Chemical Equation Presented) Aflexible method for the diastereoselective total synthesis of the pyrrolizidine alkaloids uniflorine A, casuarine, australine, and 3-epi-australine and the unnatural epimer 3,7-di-epi-australine from a common chiral 2,5-dihydropyrrole precursor is described.

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Total synthesis of uniflorine A, casuarine, australine, 3-epi-australine, and 3,7-di-epi-australine from a common precursor

Abstract

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