Towards a self-assembled honeycomb structure via diaminotriptycene metal complexes

Qian Liang; Jonathan H. Chong; Nicholas G. White; Zhen Zhao; Mark J. Maclachlan

doi:10.1039/c3dt51330k

Towards a self-assembled honeycomb structure via diaminotriptycene metal complexes

Qian Liang, Jonathan H. Chong, Nicholas G. White, Zhen Zhao, Mark J. Maclachlan^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

We illustrate a new approach toward the synthesis of a porous supramolecular honeycomb based on triptycene. A coordination polymer has been prepared where the triptycene groups are linked through triptycenesemiquinonediimine platinum complexes, but the product is disordered rather than the intended honeycomb structure. A model platinum complex and its ¹⁵N-labeled isotopomer have been prepared and characterized.

Original language	English
Pages (from-to)	16474-16477
Number of pages	4
Journal	Dalton Transactions
Volume	42
Issue number	47
DOIs	https://doi.org/10.1039/c3dt51330k
Publication status	Published - 21 Dec 2013
Externally published	Yes

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title = "Towards a self-assembled honeycomb structure via diaminotriptycene metal complexes",

abstract = "We illustrate a new approach toward the synthesis of a porous supramolecular honeycomb based on triptycene. A coordination polymer has been prepared where the triptycene groups are linked through triptycenesemiquinonediimine platinum complexes, but the product is disordered rather than the intended honeycomb structure. A model platinum complex and its 15N-labeled isotopomer have been prepared and characterized.",

author = "Qian Liang and Chong, {Jonathan H.} and White, {Nicholas G.} and Zhen Zhao and Maclachlan, {Mark J.}",

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T1 - Towards a self-assembled honeycomb structure via diaminotriptycene metal complexes

AU - Liang, Qian

AU - Chong, Jonathan H.

AU - White, Nicholas G.

AU - Zhao, Zhen

AU - Maclachlan, Mark J.

PY - 2013/12/21

Y1 - 2013/12/21

N2 - We illustrate a new approach toward the synthesis of a porous supramolecular honeycomb based on triptycene. A coordination polymer has been prepared where the triptycene groups are linked through triptycenesemiquinonediimine platinum complexes, but the product is disordered rather than the intended honeycomb structure. A model platinum complex and its 15N-labeled isotopomer have been prepared and characterized.

AB - We illustrate a new approach toward the synthesis of a porous supramolecular honeycomb based on triptycene. A coordination polymer has been prepared where the triptycene groups are linked through triptycenesemiquinonediimine platinum complexes, but the product is disordered rather than the intended honeycomb structure. A model platinum complex and its 15N-labeled isotopomer have been prepared and characterized.

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U2 - 10.1039/c3dt51330k

DO - 10.1039/c3dt51330k

M3 - Article

SN - 1477-9226

VL - 42

SP - 16474

EP - 16477

JO - Dalton Transactions

JF - Dalton Transactions

IS - 47

ER -

Towards a self-assembled honeycomb structure via diaminotriptycene metal complexes

Abstract

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