Tracing the provenance and recrystallization processes of the Earth's oldest detritus at Mt. Narryer and Jack Hills, Western Australia: An in situ Sm-Nd isotopic study of monazite

Mount Narryer and Jack Hills metasedimentary rocks in the Narryer Gneiss Complex of the Yilgarn Craton, Western Australia, contain zircons with ages up to 4.4Ga, the oldest known crustal materials on Earth, and monazites up to 3.6Ga. In this study, we have investigated ¹⁴⁷Sm-¹⁴³Nd systematics of detrital and metamorphic monazites from these metasedimentary rocks using laser ablation-multicollector-inductively coupled plasma mass spectrometry (LA-MC-ICPMS). All detrital monazites have negative initial ΕNd(t) values, indicating that their parental magmas formed by remelting of older crustal materials. A comparison between the initial ΕNd(t) values of the detrital monazites and granitoids in the Narryer Gneiss Complex indicates that the Mt. Narryer and Jack Hills sediments were partly derived from the most isotopically enriched surrounding granitoids with ages of ca. 3.6 and 3.3Ga. The metamorphic monazites generally have lower initial ΕNd(t) values when compared to the detrital monazites. However, the detrital and metamorphic monazites show similar distributions of ΕNd(t) at the ages of sediment deposition (3.28Ga for Mt. Narryer and 3.05Ga for Jack Hills). In addition, multiple analyses on single monazite grains having core-rim structures reveal that the cores and the recrystallized rims had identical Nd isotopic compositions at the time of recrystallization. These findings indicate that older monazites are source of light rare earth elements for younger metamorphic monazite formation and, therefore, that monazite can inherit its primary Sm-Nd isotopic signature during the recrystallization processes. We calculated the Nd model ages for all analyzed monazites to estimate crustal residence time of their source materials. We find that no igneous monazites older than 4.0Ga were recrystallized to form the monazites. This implies that the lack of Hadean monazites is not due to recrystallization of ancient monazites during later metamorphism, but due to high-Ca compositions of the parental magmas of Hadean detritus, which prevent growth of magmatic monazite.