Trans-(Acetonitrile)bis[1,2-bis(diphenylphosphino)ethane- κ2P,P′](phenylethynyl)-ruthenium(II) hexafluorophosphate ethanol hemisolvate

Anthony C. Willis; Clem E. Powell; Mark G. Humphrey

doi:10.1107/S1600536806035252

Trans-(Acetonitrile)bis[1,2-bis(diphenylphosphino)ethane- κ²P,P′](phenylethynyl)-ruthenium(II) hexafluorophosphate ethanol hemisolvate

Anthony C. Willis, Clem E. Powell, Mark G. Humphrey^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The title compound, [Ru(C₈H₅)(C₂H ₃N)(C₂₆H₂₄P₂)₂]PF ₆·-0.5C₂H₅OH, comprises a pseudo-octahedral ruthenium complex cation with two bidentate diphosphine ligands and trans-disposed acetonitrile and phenylethynyl ligands, together with a disordered hexafluorophosphate anion and a disordered ethanol solvent molecule.

Original language	English
Pages (from-to)	m2473-m2475
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	62
Issue number	10
DOIs	https://doi.org/10.1107/S1600536806035252
Publication status	Published - Oct 2006

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title = "Trans-(Acetonitrile)bis[1,2-bis(diphenylphosphino)ethane- κ2P,P′](phenylethynyl)-ruthenium(II) hexafluorophosphate ethanol hemisolvate",

abstract = "The title compound, [Ru(C8H5)(C2H 3N)(C26H24P2)2]PF 6·-0.5C2H5OH, comprises a pseudo-octahedral ruthenium complex cation with two bidentate diphosphine ligands and trans-disposed acetonitrile and phenylethynyl ligands, together with a disordered hexafluorophosphate anion and a disordered ethanol solvent molecule.",

author = "Willis, {Anthony C.} and Powell, {Clem E.} and Humphrey, {Mark G.}",

year = "2006",

month = oct,

doi = "10.1107/S1600536806035252",

language = "English",

volume = "62",

pages = "m2473--m2475",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "10",

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TY - JOUR

T1 - Trans-(Acetonitrile)bis[1,2-bis(diphenylphosphino)ethane- κ2P,P′](phenylethynyl)-ruthenium(II) hexafluorophosphate ethanol hemisolvate

AU - Willis, Anthony C.

AU - Powell, Clem E.

AU - Humphrey, Mark G.

PY - 2006/10

Y1 - 2006/10

N2 - The title compound, [Ru(C8H5)(C2H 3N)(C26H24P2)2]PF 6·-0.5C2H5OH, comprises a pseudo-octahedral ruthenium complex cation with two bidentate diphosphine ligands and trans-disposed acetonitrile and phenylethynyl ligands, together with a disordered hexafluorophosphate anion and a disordered ethanol solvent molecule.

AB - The title compound, [Ru(C8H5)(C2H 3N)(C26H24P2)2]PF 6·-0.5C2H5OH, comprises a pseudo-octahedral ruthenium complex cation with two bidentate diphosphine ligands and trans-disposed acetonitrile and phenylethynyl ligands, together with a disordered hexafluorophosphate anion and a disordered ethanol solvent molecule.

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U2 - 10.1107/S1600536806035252

DO - 10.1107/S1600536806035252

M3 - Article

SN - 1600-5368

VL - 62

SP - m2473-m2475

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 10

ER -

Trans-(Acetonitrile)bis[1,2-bis(diphenylphosphino)ethane- κ²P,P′](phenylethynyl)-ruthenium(II) hexafluorophosphate ethanol hemisolvate

Abstract

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