Transition metal-alkane θ-complexes with oxygen donor Co-ligands

Rowan D. Young; Anthony F. Hill; Warwick Hillier; Graham E. Ball

doi:10.1021/ja203470y

Transition metal-alkane θ-complexes with oxygen donor Co-ligands

Rowan D. Young, Anthony F. Hill^*, Warwick Hillier, Graham E. Ball

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

33 Citations (Scopus)

Abstract

A new family of long-lived alkane θ-complexes of the type (L _OEt)Re(CO)₂(alkane) [alkane = cyclopentane, cyclohexane, pentane; L_OEt = cyclopentadienyltris(diethylphosphito)cobaltate(III)] has been observed using both IR and NMR spectroscopies and computationally interrogated with DFT methods. The oxygen-rich coordination spheres makes these complexes perhaps more relevant as models for intermediates in metal oxide mediated hydrocarbon transformations than other known alkane θ-complexes.

Original language	English
Pages (from-to)	13806-13809
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	133
Issue number	35
DOIs	https://doi.org/10.1021/ja203470y
Publication status	Published - 7 Sept 2011

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title = "Transition metal-alkane θ-complexes with oxygen donor Co-ligands",

abstract = "A new family of long-lived alkane θ-complexes of the type (L OEt)Re(CO)2(alkane) [alkane = cyclopentane, cyclohexane, pentane; LOEt = cyclopentadienyltris(diethylphosphito)cobaltate(III)] has been observed using both IR and NMR spectroscopies and computationally interrogated with DFT methods. The oxygen-rich coordination spheres makes these complexes perhaps more relevant as models for intermediates in metal oxide mediated hydrocarbon transformations than other known alkane θ-complexes.",

author = "Young, {Rowan D.} and Hill, {Anthony F.} and Warwick Hillier and Ball, {Graham E.}",

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AU - Young, Rowan D.

AU - Hill, Anthony F.

AU - Hillier, Warwick

AU - Ball, Graham E.

PY - 2011/9/7

Y1 - 2011/9/7

N2 - A new family of long-lived alkane θ-complexes of the type (L OEt)Re(CO)2(alkane) [alkane = cyclopentane, cyclohexane, pentane; LOEt = cyclopentadienyltris(diethylphosphito)cobaltate(III)] has been observed using both IR and NMR spectroscopies and computationally interrogated with DFT methods. The oxygen-rich coordination spheres makes these complexes perhaps more relevant as models for intermediates in metal oxide mediated hydrocarbon transformations than other known alkane θ-complexes.

AB - A new family of long-lived alkane θ-complexes of the type (L OEt)Re(CO)2(alkane) [alkane = cyclopentane, cyclohexane, pentane; LOEt = cyclopentadienyltris(diethylphosphito)cobaltate(III)] has been observed using both IR and NMR spectroscopies and computationally interrogated with DFT methods. The oxygen-rich coordination spheres makes these complexes perhaps more relevant as models for intermediates in metal oxide mediated hydrocarbon transformations than other known alkane θ-complexes.

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U2 - 10.1021/ja203470y

DO - 10.1021/ja203470y

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SP - 13806

EP - 13809

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 35

ER -

Transition metal-alkane θ-complexes with oxygen donor Co-ligands

Abstract

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