TY - JOUR
T1 - Trigonal Planar Heteroleptic Lanthanide(III) Bis(silyl)amide Complexes Containing Aminoxyl Radicals and Anions
AU - Gransbury, Gemma K.
AU - Nicholas, Hannah M.
AU - Murphy, Siobhan R.
AU - Emerson-King, Jack
AU - Vonci, Michele
AU - Goodwin, Conrad A. P.
AU - Winpenny, Richard E. P.
AU - Chilton, Nicholas F.
AU - Giansiracusa, Marcus J.
AU - Mills, David P.
N1 - Publisher: American Chemical Society
PY - 2024/11/1
Y1 - 2024/11/1
N2 - Modulation of the crystal field (CF) in lanthanide (Ln) complexes can enhance optical and magnetic properties, and large CF splitting can be achieved with low coordination numbers in specific geometries. We previously reported that the homoleptic near-linear Sm2+ complex [SmIIN(SiiPr3)22] (1-Sm) is oxidized by the 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO•) radical to give the heteroleptic, approximately trigonal planar Sm3+ complex, [SmIIIN(SiiPr3)22(TEMPO–)] (2-Sm). Here, we report the synthesis of homologous [LnIIIN(SiiPr3)22(TEMPO–)] (2-Ln; Ln = Tm, Yb) complexes by the oxidation of the parent [LnN(SiiPr3)22] (1-Ln; Ln = Tm, Yb) with TEMPO•; complexes 2-Ln all contain TEMPO– anions. The homoleptic bent Ln3+ complexes [LnIIIN(SiiPr3)22][B(C6F5)4] (3-Ln; Ln = Sm, Tm, Yb) were also treated with TEMPO• to yield the heteroleptic, approximately trigonal planar Ln3+ complexes [LnIIIN(SiiPr3)22(TEMPO•)][B(C6F5)4] (4-Ln; Ln = Sm, Tm, Yb); the cations of 4-Ln all contain TEMPO• radicals. We have compared the electronic structures of the two geometrically similar families of Ln3+ complexes with the TEMPO– anion (2-Ln) or TEMPO• radical (4-Ln) using a combination of UV–vis-NIR and EPR spectroscopy, magnetic measurements, and ab initio calculations. These studies revealed no single-molecule magnet behavior for 2-Yb despite evidence for sizable CF splitting and a high degree of purity of the ground stabilized mJ = textbar±7/2⟩ state, while the radical TEMPO• in 4-Yb did not significantly improve performance.
AB - Modulation of the crystal field (CF) in lanthanide (Ln) complexes can enhance optical and magnetic properties, and large CF splitting can be achieved with low coordination numbers in specific geometries. We previously reported that the homoleptic near-linear Sm2+ complex [SmIIN(SiiPr3)22] (1-Sm) is oxidized by the 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO•) radical to give the heteroleptic, approximately trigonal planar Sm3+ complex, [SmIIIN(SiiPr3)22(TEMPO–)] (2-Sm). Here, we report the synthesis of homologous [LnIIIN(SiiPr3)22(TEMPO–)] (2-Ln; Ln = Tm, Yb) complexes by the oxidation of the parent [LnN(SiiPr3)22] (1-Ln; Ln = Tm, Yb) with TEMPO•; complexes 2-Ln all contain TEMPO– anions. The homoleptic bent Ln3+ complexes [LnIIIN(SiiPr3)22][B(C6F5)4] (3-Ln; Ln = Sm, Tm, Yb) were also treated with TEMPO• to yield the heteroleptic, approximately trigonal planar Ln3+ complexes [LnIIIN(SiiPr3)22(TEMPO•)][B(C6F5)4] (4-Ln; Ln = Sm, Tm, Yb); the cations of 4-Ln all contain TEMPO• radicals. We have compared the electronic structures of the two geometrically similar families of Ln3+ complexes with the TEMPO– anion (2-Ln) or TEMPO• radical (4-Ln) using a combination of UV–vis-NIR and EPR spectroscopy, magnetic measurements, and ab initio calculations. These studies revealed no single-molecule magnet behavior for 2-Yb despite evidence for sizable CF splitting and a high degree of purity of the ground stabilized mJ = textbar±7/2⟩ state, while the radical TEMPO• in 4-Yb did not significantly improve performance.
U2 - 10.1021/acs.inorgchem.4c03281
DO - 10.1021/acs.inorgchem.4c03281
M3 - Article
SN - 0020-1669
JO - Inorganic Chemistry
JF - Inorganic Chemistry
ER -