Trigonal prismatic metal complexes: A not so rare coordination geometry?

Leighton J. Alcock; Germán Cavigliasso; Anthony C. Willis; Robert Stranger; Stephen F. Ralph

doi:10.1039/c6dt01176d

Trigonal prismatic metal complexes: A not so rare coordination geometry?

Leighton J. Alcock, Germán Cavigliasso, Anthony C. Willis, Robert Stranger, Stephen F. Ralph^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

The solid state structures of two metal complexes of a hexaamine macrobicyclic ligand, in which the metal ion has an exact trigonal prismatic geometry, have been determined. Theoretical calculations showed this is the most stable geometry for d⁰, d¹⁰ and high spin d⁵ metal complexes of the ligand with M-N bond distances >∼2.35 Å.

Original language	English
Pages (from-to)	9036-9040
Number of pages	5
Journal	Dalton Transactions
Volume	45
Issue number	22
DOIs	https://doi.org/10.1039/c6dt01176d
Publication status	Published - 2016

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@article{52c980db23924c678556af3031163921,

title = "Trigonal prismatic metal complexes: A not so rare coordination geometry?",

abstract = "The solid state structures of two metal complexes of a hexaamine macrobicyclic ligand, in which the metal ion has an exact trigonal prismatic geometry, have been determined. Theoretical calculations showed this is the most stable geometry for d0, d10 and high spin d5 metal complexes of the ligand with M-N bond distances >∼2.35 {\AA}.",

author = "Alcock, \{Leighton J.\} and Germ{\'a}n Cavigliasso and Willis, \{Anthony C.\} and Robert Stranger and Ralph, \{Stephen F.\}",

note = "Publisher Copyright: {\textcopyright} 2016 The Royal Society of Chemistry.",

year = "2016",

doi = "10.1039/c6dt01176d",

language = "English",

volume = "45",

pages = "9036--9040",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "22",

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TY - JOUR

T1 - Trigonal prismatic metal complexes

T2 - A not so rare coordination geometry?

AU - Alcock, Leighton J.

AU - Cavigliasso, Germán

AU - Willis, Anthony C.

AU - Stranger, Robert

AU - Ralph, Stephen F.

PY - 2016

Y1 - 2016

N2 - The solid state structures of two metal complexes of a hexaamine macrobicyclic ligand, in which the metal ion has an exact trigonal prismatic geometry, have been determined. Theoretical calculations showed this is the most stable geometry for d0, d10 and high spin d5 metal complexes of the ligand with M-N bond distances >∼2.35 Å.

AB - The solid state structures of two metal complexes of a hexaamine macrobicyclic ligand, in which the metal ion has an exact trigonal prismatic geometry, have been determined. Theoretical calculations showed this is the most stable geometry for d0, d10 and high spin d5 metal complexes of the ligand with M-N bond distances >∼2.35 Å.

UR - https://www.scopus.com/pages/publications/84973370412

U2 - 10.1039/c6dt01176d

DO - 10.1039/c6dt01176d

M3 - Article

SN - 1477-9226

VL - 45

SP - 9036

EP - 9040

JO - Dalton Transactions

JF - Dalton Transactions

IS - 22

ER -

Trigonal prismatic metal complexes: A not so rare coordination geometry?

Abstract

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