Triple-point wetting and liquid condensation in a slit pore

Ying Qiao; Hugo K. Christenson

doi:10.1103/PhysRevLett.83.1371

Triple-point wetting and liquid condensation in a slit pore

Ying Qiao, Hugo K. Christenson^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

We have used multiple-beam interferometry to study the temperature dependence of tert-butanol adsorption from vapor on mica, at an isolated surface and in a slit pore. The film thickness at one surface increases from 2 nm for 17-24 °C to >7 nm above the triple point T_tr (25.5 °C). Concomitantly, the surface separation at which the slit fills with liquid increases from 11 to 27 nm. These results show for the first time how a continuous triple-point wetting transition at one surface and suppression of the freezing transition in a slit pore affect capillary condensation near T_tr.

Original language	English
Pages (from-to)	1371-1374
Number of pages	4
Journal	Physical Review Letters
Volume	83
Issue number	7
DOIs	https://doi.org/10.1103/PhysRevLett.83.1371
Publication status	Published - 1 Jan 1999

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10.1103/PhysRevLett.83.1371

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title = "Triple-point wetting and liquid condensation in a slit pore",

abstract = "We have used multiple-beam interferometry to study the temperature dependence of tert-butanol adsorption from vapor on mica, at an isolated surface and in a slit pore. The film thickness at one surface increases from 2 nm for 17-24 °C to >7 nm above the triple point Ttr (25.5 °C). Concomitantly, the surface separation at which the slit fills with liquid increases from 11 to 27 nm. These results show for the first time how a continuous triple-point wetting transition at one surface and suppression of the freezing transition in a slit pore affect capillary condensation near Ttr.",

author = "Ying Qiao and Christenson, \{Hugo K.\}",

year = "1999",

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AU - Christenson, Hugo K.

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AB - We have used multiple-beam interferometry to study the temperature dependence of tert-butanol adsorption from vapor on mica, at an isolated surface and in a slit pore. The film thickness at one surface increases from 2 nm for 17-24 °C to >7 nm above the triple point Ttr (25.5 °C). Concomitantly, the surface separation at which the slit fills with liquid increases from 11 to 27 nm. These results show for the first time how a continuous triple-point wetting transition at one surface and suppression of the freezing transition in a slit pore affect capillary condensation near Ttr.

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JO - Physical Review Letters

JF - Physical Review Letters

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Triple-point wetting and liquid condensation in a slit pore

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