TY - JOUR
T1 - Tungsten-platinum μ-carbido and μ-methylidyne complexes
AU - Frogley, Benjamin J.
AU - Hill, Anthony F.
N1 - Publisher Copyright:
© 2019 The Royal Society of Chemistry.
PY - 2019
Y1 - 2019
N2 - Reactions of the lithiocarbyne [W]CLi ([W] = W(CO)2(Tp∗); Tp∗ = tris(dimethylpyrazolyl)borate) with divalent platinum complexes [PtCl(terpy)]PF6, [PtCl2(η-C4R4)] (R = Me, Et), and [PtCl2(phen)] afford access to μ-carbido, μ-methylidyne and carbyne-based metallo-ligand complexes [Pt(C[W])(terpy)]PF6, [Pt(μ-HC[W])2] and [Pt(C[W])Cl(phen-C[W]-2)], respectively, the last of which provides a rare example of intermolecular organometallic nucleophilic attack at coordinated phenanthroline.
AB - Reactions of the lithiocarbyne [W]CLi ([W] = W(CO)2(Tp∗); Tp∗ = tris(dimethylpyrazolyl)borate) with divalent platinum complexes [PtCl(terpy)]PF6, [PtCl2(η-C4R4)] (R = Me, Et), and [PtCl2(phen)] afford access to μ-carbido, μ-methylidyne and carbyne-based metallo-ligand complexes [Pt(C[W])(terpy)]PF6, [Pt(μ-HC[W])2] and [Pt(C[W])Cl(phen-C[W]-2)], respectively, the last of which provides a rare example of intermolecular organometallic nucleophilic attack at coordinated phenanthroline.
UR - http://www.scopus.com/inward/record.url?scp=85073126539&partnerID=8YFLogxK
U2 - 10.1039/c9cc06472a
DO - 10.1039/c9cc06472a
M3 - Article
SN - 1359-7345
VL - 55
SP - 12400
EP - 12403
JO - Chemical Communications
JF - Chemical Communications
IS - 82
ER -