Tungsten-platinum μ-carbido and μ-methylidyne complexes

Benjamin J. Frogley; Anthony F. Hill

doi:10.1039/c9cc06472a

Tungsten-platinum μ-carbido and μ-methylidyne complexes

Benjamin J. Frogley
, Anthony F. Hill^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

Reactions of the lithiocarbyne [W]CLi ([W] = W(CO)₂(Tp∗); Tp∗ = tris(dimethylpyrazolyl)borate) with divalent platinum complexes [PtCl(terpy)]PF₆, [PtCl₂(η-C₄R₄)] (R = Me, Et), and [PtCl₂(phen)] afford access to μ-carbido, μ-methylidyne and carbyne-based metallo-ligand complexes [Pt(C[W])(terpy)]PF₆, [Pt(μ-HC[W])₂] and [Pt(C[W])Cl(phen-C[W]-2)], respectively, the last of which provides a rare example of intermolecular organometallic nucleophilic attack at coordinated phenanthroline.

Original language	English
Pages (from-to)	12400-12403
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	82
DOIs	https://doi.org/10.1039/c9cc06472a
Publication status	Published - 2019

Access to Document

10.1039/c9cc06472a

Cite this

@article{ec8bf294e1774ae3b99df3b1508a571c,

title = "Tungsten-platinum μ-carbido and μ-methylidyne complexes",

abstract = "Reactions of the lithiocarbyne [W]CLi ([W] = W(CO)2(Tp∗); Tp∗ = tris(dimethylpyrazolyl)borate) with divalent platinum complexes [PtCl(terpy)]PF6, [PtCl2(η-C4R4)] (R = Me, Et), and [PtCl2(phen)] afford access to μ-carbido, μ-methylidyne and carbyne-based metallo-ligand complexes [Pt(C[W])(terpy)]PF6, [Pt(μ-HC[W])2] and [Pt(C[W])Cl(phen-C[W]-2)], respectively, the last of which provides a rare example of intermolecular organometallic nucleophilic attack at coordinated phenanthroline.",

author = "Frogley, \{Benjamin J.\} and Hill, \{Anthony F.\}",

note = "Publisher Copyright: {\textcopyright} 2019 The Royal Society of Chemistry.",

year = "2019",

doi = "10.1039/c9cc06472a",

language = "English",

volume = "55",

pages = "12400--12403",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "82",

}

TY - JOUR

T1 - Tungsten-platinum μ-carbido and μ-methylidyne complexes

AU - Frogley, Benjamin J.

AU - Hill, Anthony F.

PY - 2019

Y1 - 2019

N2 - Reactions of the lithiocarbyne [W]CLi ([W] = W(CO)2(Tp∗); Tp∗ = tris(dimethylpyrazolyl)borate) with divalent platinum complexes [PtCl(terpy)]PF6, [PtCl2(η-C4R4)] (R = Me, Et), and [PtCl2(phen)] afford access to μ-carbido, μ-methylidyne and carbyne-based metallo-ligand complexes [Pt(C[W])(terpy)]PF6, [Pt(μ-HC[W])2] and [Pt(C[W])Cl(phen-C[W]-2)], respectively, the last of which provides a rare example of intermolecular organometallic nucleophilic attack at coordinated phenanthroline.

AB - Reactions of the lithiocarbyne [W]CLi ([W] = W(CO)2(Tp∗); Tp∗ = tris(dimethylpyrazolyl)borate) with divalent platinum complexes [PtCl(terpy)]PF6, [PtCl2(η-C4R4)] (R = Me, Et), and [PtCl2(phen)] afford access to μ-carbido, μ-methylidyne and carbyne-based metallo-ligand complexes [Pt(C[W])(terpy)]PF6, [Pt(μ-HC[W])2] and [Pt(C[W])Cl(phen-C[W]-2)], respectively, the last of which provides a rare example of intermolecular organometallic nucleophilic attack at coordinated phenanthroline.

UR - https://www.scopus.com/pages/publications/85073126539

U2 - 10.1039/c9cc06472a

DO - 10.1039/c9cc06472a

M3 - Article

SN - 1359-7345

VL - 55

SP - 12400

EP - 12403

JO - Chemical Communications

JF - Chemical Communications

IS - 82

ER -

Tungsten-platinum μ-carbido and μ-methylidyne complexes

Abstract

Access to Document

Other files and links

Fingerprint

Cite this