Two Counterintuitive Routes to an Iron Alkylidyne Complex

Stephen Anderson; Anthony F. Hill

doi:10.1021/om00004a007

Two Counterintuitive Routes to an Iron Alkylidyne Complex

Stephen Anderson, Anthony F. Hill^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

The cationic aminomethylidyne complex [Fe- (≡CNⁱPr₂)(CO)₃(PPh₃)]⁺ has been prepared by two unexpected routes: (i) Iodination of the carbamoyl complex [Fe(η²-OCNⁱPr₂)(CF₃)(CO)₂(PPh₃)] and (ii) O-trifluoroacetylation of the carbamoylate [Fe{C(=O)NⁱPr₂}(CO₄]-Li, a reaction which shows an unusual solvent dependence.

Original language	English
Pages (from-to)	1562-1564
Number of pages	3
Journal	Organometallics
Volume	14
Issue number	4
DOIs	https://doi.org/10.1021/om00004a007
Publication status	Published - Apr 1995
Externally published	Yes

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title = "Two Counterintuitive Routes to an Iron Alkylidyne Complex",

abstract = "The cationic aminomethylidyne complex [Fe- (≡CNiPr2)(CO)3(PPh3)]+ has been prepared by two unexpected routes: (i) Iodination of the carbamoyl complex [Fe(η2-OCNiPr2)(CF3)(CO)2(PPh3)] and (ii) O-trifluoroacetylation of the carbamoylate [Fe{C(=O)NiPr2}(CO4]-Li, a reaction which shows an unusual solvent dependence.",

author = "Stephen Anderson and Hill, {Anthony F.}",

year = "1995",

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language = "English",

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AU - Anderson, Stephen

AU - Hill, Anthony F.

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N2 - The cationic aminomethylidyne complex [Fe- (≡CNiPr2)(CO)3(PPh3)]+ has been prepared by two unexpected routes: (i) Iodination of the carbamoyl complex [Fe(η2-OCNiPr2)(CF3)(CO)2(PPh3)] and (ii) O-trifluoroacetylation of the carbamoylate [Fe{C(=O)NiPr2}(CO4]-Li, a reaction which shows an unusual solvent dependence.

AB - The cationic aminomethylidyne complex [Fe- (≡CNiPr2)(CO)3(PPh3)]+ has been prepared by two unexpected routes: (i) Iodination of the carbamoyl complex [Fe(η2-OCNiPr2)(CF3)(CO)2(PPh3)] and (ii) O-trifluoroacetylation of the carbamoylate [Fe{C(=O)NiPr2}(CO4]-Li, a reaction which shows an unusual solvent dependence.

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U2 - 10.1021/om00004a007

DO - 10.1021/om00004a007

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VL - 14

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JO - Organometallics

JF - Organometallics

IS - 4

ER -

Two Counterintuitive Routes to an Iron Alkylidyne Complex

Abstract

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