U-series dating of carbonates using inductively coupled plasma-quadrupole mass spectrometry

We describe an analytical methodology to quantify ²³⁸U-²³⁴U and ²³⁰Th using isotope-dilution systematics and inductively coupled plasma-quadrupole mass spectrometry (ICP-QMS) for geochronological purposes. This required characterization of the mass spectrometer detector performance over a large dynamic range, including a careful calibration between pulse and analogue ion-counting modes. Our methodology gives an analytical precision for ²³⁴U/²³⁸U and ²³⁰Th/²³⁸U of 4‰ and 7‰ (2 × standard error), respectively, and yields ²³⁰Th-ages with 4-5% uncertainty from 500 ng of ²³⁸U. We tested our methodology by analyzing carbonate samples (corals and speleothems) which were previously dated using MC-ICPMS; excellent agreement between both techniques was obtained. Our results indicate that ICP-QMS is suitable to obtain valuable meaningful geochronological data, but it is limited to dating samples older than 1 ka, and younger than 400 ka. Our methodology thus represents an attractive alternative to obtain geochonological data to select the most interesting samples prior to high-precision analysis. Moreover, such data would also valuable to build preliminary age-models, which can be further complemented with high-precision analyses.