Undecacarbonyl(methylcyclopenta-dienyl)-tetrahedro-triiridiummolybdenum, undecacarbonyl(tetramethyl-cyclopentadienyl)-tetrahedro-triiridiummolybdenum and undeca-carbonyl(pentamethylcyclopentadienyl)-tetrahedro-triiridiummolybdenum

Nigel T. Lucas; Ian R. Whittall; Mark G. Humphrey

doi:10.1107/S0108270101020558

Undecacarbonyl(methylcyclopenta-dienyl)-tetrahedro-triiridiummolybdenum, undecacarbonyl(tetramethyl-cyclopentadienyl)-tetrahedro-triiridiummolybdenum and undeca-carbonyl(pentamethylcyclopentadienyl)-tetrahedro-triiridiummolybdenum

Nigel T. Lucas, Ian R. Whittall, Mark G. Humphrey^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The crystal structure of the molybdenum organometallic compound complexes was studied. The alkyl cyclopentadienyl ligands provided flexibility in tuning the electronic and steric properties of the complex. The decreasing Mo-Co distances on increasing both steric bulk and electronic-donating properties of the alkylcyclopentadienyl ligands showed that electronic factors dominated over steric consideration of the ligand disposition.

Original language	English
Pages (from-to)	m249-m251
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	58
Issue number	4
DOIs	https://doi.org/10.1107/S0108270101020558
Publication status	Published - Apr 2002

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Lucas, N. T., Whittall, I. R., & Humphrey, M. G. (2002). Undecacarbonyl(methylcyclopenta-dienyl)-tetrahedro-triiridiummolybdenum, undecacarbonyl(tetramethyl-cyclopentadienyl)-tetrahedro-triiridiummolybdenum and undeca-carbonyl(pentamethylcyclopentadienyl)-tetrahedro-triiridiummolybdenum. Acta Crystallographica Section C: Crystal Structure Communications, 58(4), m249-m251. https://doi.org/10.1107/S0108270101020558

Lucas, Nigel T. ; Whittall, Ian R. ; Humphrey, Mark G. / Undecacarbonyl(methylcyclopenta-dienyl)-tetrahedro-triiridiummolybdenum, undecacarbonyl(tetramethyl-cyclopentadienyl)-tetrahedro-triiridiummolybdenum and undeca-carbonyl(pentamethylcyclopentadienyl)-tetrahedro-triiridiummolybdenum. In: Acta Crystallographica Section C: Crystal Structure Communications. 2002 ; Vol. 58, No. 4. pp. m249-m251.

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title = "Undecacarbonyl(methylcyclopenta-dienyl)-tetrahedro-triiridiummolybdenum, undecacarbonyl(tetramethyl-cyclopentadienyl)-tetrahedro-triiridiummolybdenum and undeca-carbonyl(pentamethylcyclopentadienyl)-tetrahedro-triiridiummolybdenum",

abstract = "The crystal structure of the molybdenum organometallic compound complexes was studied. The alkyl cyclopentadienyl ligands provided flexibility in tuning the electronic and steric properties of the complex. The decreasing Mo-Co distances on increasing both steric bulk and electronic-donating properties of the alkylcyclopentadienyl ligands showed that electronic factors dominated over steric consideration of the ligand disposition.",

author = "Lucas, {Nigel T.} and Whittall, {Ian R.} and Humphrey, {Mark G.}",

year = "2002",

month = apr,

doi = "10.1107/S0108270101020558",

language = "English",

volume = "58",

pages = "m249--m251",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "4",

}

Lucas, NT, Whittall, IR & Humphrey, MG 2002, 'Undecacarbonyl(methylcyclopenta-dienyl)-tetrahedro-triiridiummolybdenum, undecacarbonyl(tetramethyl-cyclopentadienyl)-tetrahedro-triiridiummolybdenum and undeca-carbonyl(pentamethylcyclopentadienyl)-tetrahedro-triiridiummolybdenum', Acta Crystallographica Section C: Crystal Structure Communications, vol. 58, no. 4, pp. m249-m251. https://doi.org/10.1107/S0108270101020558

Undecacarbonyl(methylcyclopenta-dienyl)-tetrahedro-triiridiummolybdenum, undecacarbonyl(tetramethyl-cyclopentadienyl)-tetrahedro-triiridiummolybdenum and undeca-carbonyl(pentamethylcyclopentadienyl)-tetrahedro-triiridiummolybdenum. / Lucas, Nigel T.; Whittall, Ian R.; Humphrey, Mark G.
In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 58, No. 4, 04.2002, p. m249-m251.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Undecacarbonyl(methylcyclopenta-dienyl)-tetrahedro-triiridiummolybdenum, undecacarbonyl(tetramethyl-cyclopentadienyl)-tetrahedro-triiridiummolybdenum and undeca-carbonyl(pentamethylcyclopentadienyl)-tetrahedro-triiridiummolybdenum

AU - Lucas, Nigel T.

AU - Whittall, Ian R.

AU - Humphrey, Mark G.

PY - 2002/4

Y1 - 2002/4

N2 - The crystal structure of the molybdenum organometallic compound complexes was studied. The alkyl cyclopentadienyl ligands provided flexibility in tuning the electronic and steric properties of the complex. The decreasing Mo-Co distances on increasing both steric bulk and electronic-donating properties of the alkylcyclopentadienyl ligands showed that electronic factors dominated over steric consideration of the ligand disposition.

AB - The crystal structure of the molybdenum organometallic compound complexes was studied. The alkyl cyclopentadienyl ligands provided flexibility in tuning the electronic and steric properties of the complex. The decreasing Mo-Co distances on increasing both steric bulk and electronic-donating properties of the alkylcyclopentadienyl ligands showed that electronic factors dominated over steric consideration of the ligand disposition.

UR - http://www.scopus.com/inward/record.url?scp=0036528957&partnerID=8YFLogxK

U2 - 10.1107/S0108270101020558

DO - 10.1107/S0108270101020558

M3 - Article

SN - 0108-2701

VL - 58

SP - m249-m251

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 4

ER -

Lucas NT, Whittall IR, Humphrey MG. Undecacarbonyl(methylcyclopenta-dienyl)-tetrahedro-triiridiummolybdenum, undecacarbonyl(tetramethyl-cyclopentadienyl)-tetrahedro-triiridiummolybdenum and undeca-carbonyl(pentamethylcyclopentadienyl)-tetrahedro-triiridiummolybdenum. Acta Crystallographica Section C: Crystal Structure Communications. 2002 Apr;58(4):m249-m251. doi: 10.1107/S0108270101020558

Undecacarbonyl(methylcyclopenta-dienyl)-tetrahedro-triiridiummolybdenum, undecacarbonyl(tetramethyl-cyclopentadienyl)-tetrahedro-triiridiummolybdenum and undeca-carbonyl(pentamethylcyclopentadienyl)-tetrahedro-triiridiummolybdenum

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