Understanding the relative easiness of oxidative addition of aryl and alkyl halides to palladium(0)

Alireza Ariafard; Zhenyang Lin

doi:10.1021/om060236x

Understanding the relative easiness of oxidative addition of aryl and alkyl halides to palladium(0)

Alireza Ariafard, Zhenyang Lin^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

139 Citations (Scopus)

Abstract

Density functional theory calculations were carried out to study the relative easiness of oxidative addition of aryl and alkyl halides to Pd(0). Kinetic but not thermodynamic factors were found to contribute to the better reactivity of aryl versus alkyl halides.

Original language	English
Pages (from-to)	4030-4033
Number of pages	4
Journal	Organometallics
Volume	25
Issue number	16
DOIs	https://doi.org/10.1021/om060236x
Publication status	Published - 31 Jul 2006
Externally published	Yes

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title = "Understanding the relative easiness of oxidative addition of aryl and alkyl halides to palladium(0)",

abstract = "Density functional theory calculations were carried out to study the relative easiness of oxidative addition of aryl and alkyl halides to Pd(0). Kinetic but not thermodynamic factors were found to contribute to the better reactivity of aryl versus alkyl halides.",

author = "Alireza Ariafard and Zhenyang Lin",

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AU - Lin, Zhenyang

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AB - Density functional theory calculations were carried out to study the relative easiness of oxidative addition of aryl and alkyl halides to Pd(0). Kinetic but not thermodynamic factors were found to contribute to the better reactivity of aryl versus alkyl halides.

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Understanding the relative easiness of oxidative addition of aryl and alkyl halides to palladium(0)

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