Abstract
The reaction of the new platinaboratrane salt [PtH(PTol3){B(mt) 3}]Cl(Pt→B)8 (mt = methimazolyl, Tol = C 6H4Me-4) with 2 equivalents of PR3 (R = Me, Et) affords, via hydride migration to boron and ligand substitution, the salts [Pt(PR3)2{κ2-S,S′-HB(mt) 3}]Cl, which slowly undergo B-H reactivation, to afford, ultimately, the platinaboratrane salts [PtH(PR3){B(mt)3}]Cl(Pt→B) 8.
Original language | English |
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Pages (from-to) | 201-203 |
Number of pages | 3 |
Journal | Dalton Transactions |
Issue number | 2 |
DOIs | |
Publication status | Published - 2008 |