Unlocking the metallaboratrane cage: Reversible B-H activation in platinaboratranes

Ian R. Crossley; Anthony F. Hill

doi:10.1039/b712058c

Unlocking the metallaboratrane cage: Reversible B-H activation in platinaboratranes

Ian R. Crossley
, Anthony F. Hill^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

66 Citations (Scopus)

Abstract

The reaction of the new platinaboratrane salt [PtH(PTol₃){B(mt) ₃}]Cl(Pt→B)⁸ (mt = methimazolyl, Tol = C ₆H₄Me-4) with 2 equivalents of PR₃ (R = Me, Et) affords, via hydride migration to boron and ligand substitution, the salts [Pt(PR₃)₂{κ²-S,S′-HB(mt) ₃}]Cl, which slowly undergo B-H reactivation, to afford, ultimately, the platinaboratrane salts [PtH(PR₃){B(mt)₃}]Cl(Pt→B) ⁸.

Original language	English
Pages (from-to)	201-203
Number of pages	3
Journal	Dalton Transactions
Issue number	2
DOIs	https://doi.org/10.1039/b712058c
Publication status	Published - 2008

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title = "Unlocking the metallaboratrane cage: Reversible B-H activation in platinaboratranes",

abstract = "The reaction of the new platinaboratrane salt [PtH(PTol3)\{B(mt) 3\}]Cl(Pt→B)8 (mt = methimazolyl, Tol = C 6H4Me-4) with 2 equivalents of PR3 (R = Me, Et) affords, via hydride migration to boron and ligand substitution, the salts [Pt(PR3)2\{κ2-S,S′-HB(mt) 3\}]Cl, which slowly undergo B-H reactivation, to afford, ultimately, the platinaboratrane salts [PtH(PR3)\{B(mt)3\}]Cl(Pt→B) 8.",

author = "Crossley, \{Ian R.\} and Hill, \{Anthony F.\}",

year = "2008",

doi = "10.1039/b712058c",

language = "English",

pages = "201--203",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "2",

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TY - JOUR

T1 - Unlocking the metallaboratrane cage

T2 - Reversible B-H activation in platinaboratranes

AU - Crossley, Ian R.

AU - Hill, Anthony F.

PY - 2008

Y1 - 2008

N2 - The reaction of the new platinaboratrane salt [PtH(PTol3){B(mt) 3}]Cl(Pt→B)8 (mt = methimazolyl, Tol = C 6H4Me-4) with 2 equivalents of PR3 (R = Me, Et) affords, via hydride migration to boron and ligand substitution, the salts [Pt(PR3)2{κ2-S,S′-HB(mt) 3}]Cl, which slowly undergo B-H reactivation, to afford, ultimately, the platinaboratrane salts [PtH(PR3){B(mt)3}]Cl(Pt→B) 8.

AB - The reaction of the new platinaboratrane salt [PtH(PTol3){B(mt) 3}]Cl(Pt→B)8 (mt = methimazolyl, Tol = C 6H4Me-4) with 2 equivalents of PR3 (R = Me, Et) affords, via hydride migration to boron and ligand substitution, the salts [Pt(PR3)2{κ2-S,S′-HB(mt) 3}]Cl, which slowly undergo B-H reactivation, to afford, ultimately, the platinaboratrane salts [PtH(PR3){B(mt)3}]Cl(Pt→B) 8.

UR - https://www.scopus.com/pages/publications/37249028228

U2 - 10.1039/b712058c

DO - 10.1039/b712058c

M3 - Article

SN - 1477-9226

SP - 201

EP - 203

JO - Dalton Transactions

JF - Dalton Transactions

IS - 2

ER -

Unlocking the metallaboratrane cage: Reversible B-H activation in platinaboratranes

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