Abstract
The Evans-Searles fluctuation theorem (ESFT) has been shown to be applicable in the near- and far-from-equilibrium regimes for systems with both constant and time-dependent external fields. The derivations of the ESFT have assumed that the external field has a definite parity under a time-reversal mapping. In the present paper, we confirm that the time-reversibility of the system dynamics is a necessary condition for the ESFT to hold. The manner in which the ESFT fails for systems that are not time-reversible is presented, and results are shown which demonstrate that systems which fail to satisfy the ESFT may still satisfy the Crooks relation (CR).
| Original language | English |
|---|---|
| Pages (from-to) | 1361-1368 |
| Number of pages | 8 |
| Journal | Pure and Applied Chemistry |
| Volume | 79 |
| Issue number | 8 |
| DOIs | |
| Publication status | Published - Aug 2007 |
Fingerprint
Dive into the research topics of 'Verification of time-reversibility requirement for systems satisfying the Evans-Searles fluctuation theorem'. Together they form a unique fingerprint.Cite this
- APA
- Author
- BIBTEX
- Harvard
- Standard
- RIS
- Vancouver