Very low bulk and surface recombination in oxidized silicon wafers

Bulk and surface processes determine the recombination rate in crystalline silicon wafers. In this paper we report effective lifetime measurements for a variety of commercially available float-zone silicon wafers that have been carefully passivated using alnealed silicon oxide. Different substrate resistivities have been explored, including both p-type (boron) and n-type (phosphorus) dopants. Record high effective lifetimes of 29 and 32 ms have been measured for 90 Ω cm n-type and 150 Ω cm p-type silicon wafers, respectively. The dependence of the effective lifetime has been measured for excess carrier densities in the range of 10¹²-10¹⁷ cm^-3. These results demonstrate that very low bulk and surface recombination rates can be maintained during high-temperature oxidation (1050°C) by carefully optimizing the processing conditions.