Abstract
By using the multipolar gauge it is shown that the quantum mechanics of an electrically charged particle moving in a prescribed classical electromagnetic field (wave mechanics) may be expressed in a manner that is gauge invariant, except that the only gauge functions that are allowable in a gauge transformation are those that consist of the sum of a function that depends only on the space coordinates and a term that is the product of a constant and the time coordinate. The multipolar gauge specifies the specific set of potentials that are best suited for use in the Schroedinger equation.
Original language | English |
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Pages (from-to) | 47-51 |
Number of pages | 5 |
Journal | Journal of Molecular Structure: THEOCHEM |
Volume | 626 |
Issue number | 1-3 |
DOIs | |
Publication status | Published - 30 May 2003 |